丙酮
脱水
化学
盐酸
果糖
5-羟甲基糠醛
溶剂
动能
羟甲基糠醛
有机化学
色谱法
核化学
无机化学
糠醛
催化作用
生物化学
物理
量子力学
作者
Youdi Zhang,Haoxiang Zhu,Zefeng Ji,Youwei Cheng,Liping Zheng,Lijun Wang,Xi Li
标识
DOI:10.1021/acs.iecr.2c02934
摘要
This work presents experimental and kinetic modeling studies on fructose dehydration to 5-hydroxymethylfurfural (HMF) in the solution of mixed acetone and water, catalyzed by hydrochloric acid (HCl). A reaction scheme that added an intermediate was proposed. A corresponding kinetic model that considered the parameters, including temperature (383–423 K), initial substrate concentration (10–100 g/L), and catalyst concentration (5–60 mmol/L), was established, and the influence of solvent ratio (3–19) was also studied. The maximum yield was 91% in the ideal plug flow reactor under the optimized condition (T = 383 K, CF0 = 10 g/L, CHCl = 10 mmol/L). The model can well support the delicate reactor design since an industrially accessible HMF production process was proposed in this work.
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