有机太阳能电池
材料科学
共轭体系
光伏系统
聚合物
能量转换效率
块(置换群论)
纳米技术
光电子学
复合材料
电气工程
几何学
数学
工程类
作者
Jin‐Woo Lee,Heung-Goo Lee,Eun Sung Oh,Sunwoo Lee,Tan Ngoc‐Lan Phan,Sheng Li,Taek‐Soo Kim,Bumjoon J. Kim
出处
期刊:Joule
[Elsevier]
日期:2023-12-01
卷期号:8 (1): 204-223
被引量:28
标识
DOI:10.1016/j.joule.2023.11.005
摘要
High power conversion efficiency (PCE) and mechanical robustness are dual requisites for wearable applications of organic solar cells (OSCs). Here, we simultaneously achieve high electronic and mechanical performances in OSCs using conjugated polymer donors (PDs) consisting of electroactive rigid and soft blocks. Specifically, we integrate rigid and soft blocks to synthesize block-copolymerized PDs (D180.8-s-PEHDT0.2) having an appropriate molecular weight of D18 blocks to reach the effective conjugation length and of PEHDT blocks to achieve high mechanical properties. As a result, the D180.8-s-PEHDT0.2 OSCs achieve excellent PCE (19.0%) and stretchability (crack-onset strain [COS] = 17.2%), thus overcoming the trade-off between the photovoltaic and mechanical properties in D18- (PCE = 18.1% and COS = 1.5%) and PEHDT-based OSCs (PCE = 5.0% and COS = 30.7%). Consequently, the D180.8-s-PEHDT0.2-based intrinsically stretchable (IS)-OSCs achieve both a high PCE (14.3%) and excellent stretchability (preserving 80% of the initial PCE at 31% strain).
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