气凝胶
吸附
复合数
纳米纤维
乙烯醇
材料科学
多孔性
水溶液中的金属离子
静电纺丝
罗丹明B
咪唑酯
比表面积
化学工程
复合材料
化学
金属
催化作用
有机化学
聚合物
光催化
工程类
冶金
作者
Jizhen Huang,Zhaoqing Lu,Jiaoyang Li,Fengfeng Jia,Yafang Wang,Hua Li
出处
期刊:ACS applied polymer materials
[American Chemical Society]
日期:2023-01-27
卷期号:5 (2): 1606-1612
被引量:7
标识
DOI:10.1021/acsapm.2c02110
摘要
The public health and water ecosystems are affected by industrial wastewater, resulting in water pollution including heavy metal ions and organic matter, so that adsorbents with multiple adsorption effects are developed to achieve efficient adsorption. In this work, the porous zeolitic imidazolate framework-8 (ZIF-8) was assembled onto cellulose nanofiber (CNF)/poly(vinyl alcohol) (PVA)/aramid nanofiber (ANF) composites and the ZIF-8@CNF/PVA/ANF (ZIF-8@CPA) composite aerogel was designed and fabricated. The composite aerogel has good physical properties and optimal adsorption performance assembled with 20% ZIF-8 content. The ZIF8-20@CPA composite aerogel has high porosity of about 99.62%; the specific surface area is 120.53 m2/g, and pore size is as low as 11.82 μm with a lower volume shrinkage of 1.31%. The adsorption capacity of Cr6+ and rhodamine B about lightweight ZIF8-20@CPA composite aerogels reached 231 mg/g and 201 mg/g, respectively. Due to the 3D porous structure, electrostatic interaction, and ion synergism generated by its assembly with ZIF-8, the composite aerogels have good adsorption performance for heavy metal ions and conform to the relationship of a pseudo-second-order kinetic model. Thus, this study suggests a route to fulfill the multiple adsorbents.
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