电催化剂
分解水
析氧
催化作用
化学工程
材料科学
纳米棒
热液循环
化学
无机化学
电化学
纳米技术
电极
物理化学
有机化学
光催化
工程类
作者
Zhen Pei,Tengteng Qin,Rui Tian,Yangxin Ou,Xingzhong Guo
出处
期刊:Nanomaterials
[MDPI AG]
日期:2023-08-10
卷期号:13 (16): 2302-2302
被引量:1
摘要
Transition metal sulphide electrocatalytic materials possess the bright overall water-splitting performance of practical electrocatalytic technologies. In this study, an amethyst-like MoS2@Ni9S8/Co3S4 rod electrocatalyst was constructed via a one-step hydrothermal method with in-situ-grown ZIF-67 nanoparticles on nickel foam (NF) as a precursor. The rational design and synthesis of MoS2@Ni9S8/Co3S4 endow the catalyst with neat nanorods morphology and high conductivity. The MoS2@Ni9S8/Co3S4/NF with the amethyst-like rod structure exposes abundant active sites and displays fast electron-transfer capability. The resultant MoS2@Ni9S8/Co3S4/NF exhibits outstanding hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) electrocatalytic activities, with low overpotentials of 81.24 mV (HER) at 10 mA cm-2 and 159.67 mV (OER) at 50 mA cm-2 in 1.0 M KOH solution. The full-cell voltage of overall water splitting only achieves 1.45 V at 10 mA cm-2. The successful preparation of the amethyst-like MoS2@Ni9S8/Co3S4 rod electrocatalyst provides a reliable reference for obtaining efficient electrocatalysts for overall water splitting.
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