Transition-metal- and solvent-free regioselective hydrosilylation of alkenes and allenes enabled by catalytic sodium tert-butoxide
硅氢加成
区域选择性
催化作用
硅烷
试剂
化学
过渡金属
碱金属
溶剂
艾伦
有机化学
作者
Suresh Saini,Dharmendra K. Gupta,Ramesh Bhawar,Sheema Siddiqui,Manoj V. Mane,Shubhankar Kumar Bose
出处
期刊：Green Chemistry [The Royal Society of Chemistry] 日期：2023-01-01卷期号：25 (23): 10072-10081
标识
DOI：10.1039/d3gc03473a
摘要
An efficient and sustainable method involving alkali metal Lewis base NaO t Bu as a catalyst and diphenyl silane as a silane reagent for the hydrosilylation of vinylarenes, aliphatic alkenes and allenes with high regioselectivity has been developed.
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