Effect of Carrier Film Phase Conversion Time on Polyacrylate Polymer Electrolyte Properties in All-Solid-State LIBs

To optimize the preparation process of polymer electrolytes by in situ UV curing and improve the performance of polymer electrolytes, we investigated the effect of carrier film phase conversion time on the properties of polymer electrolyte properties in all-solid-state LIBs. We compared several carrier films with phase conversion times of 24 h, 32 h, 40 h, and 48 h. Then, the physical properties of the polymer electrolytes were characterized and the properties of the polymer electrolytes were further explored. It was concluded that the carrier membrane with a phase transition time of 40 h and the prepared electrolyte had the best performance. The ionic conductivity of the sample was 1.02 × 10−3 S/cm at 25 °C and 3.42 × 10−3 S/cm at 60 °C. At its best cycle performance, it had the highest discharge-specific capacity of 155.6 mAh/g, and after 70 cycles, the discharge-specific capacity was 152.4 mAh/g, with a capacity retention rate of 98% and a discharge efficiency close to 100%. At the same time, the thermogravimetric curves showed that the samples prepared by this process had good thermal stability which can meet the various requirements of lithium-ion batteries.