化学
配体(生物化学)
羧酸盐
丙烯酸
三角双锥分子几何
结晶学
立体化学
晶体结构
聚合物
有机化学
共聚物
生物化学
受体
作者
Mohammed Dahmani,Abderrahim Titi,Abdelkader Et-Touhami,Abderrahmane Yahyi,Rachid Touzani,Mohamed Siaj,A. Zarrouk,Abeer A. AlObaid,Mohamed Saadi,Seik Weng Ng,Ismail Warad
标识
DOI:10.1016/j.ica.2023.121695
摘要
The coordination reaction of Ph3SnCl with (E)-3-(thiophen-2-yl)acrylic acid as simple –COOH acid ligand in (Et)3N medium leads to formation of {[(Ph)3SnCl)2COO]-[Et3NH]+,[(Ph)3SnCl2)]−[Et3NH]+} complex matrix in high yield for the first time. FT-IR, UV–Vis, EDX, and a single XRD were used to characterize the prepared complex. Moreover, the complex was crystallized in the triclinic system P-1 with [a = 12.5191(4); b = 13.5491(5); c = 21.9805(8); α = 100.2790(10); β = 99.1470 (10) and γ = 100.4390(10)] the lattice cell parameters. The resulting environment of each Sn(IV) centers are a distorted trigonal bipyramid geometry where the ligand carboxylate part connected both Sn(IV) centers via O,O-bi-chelate mode trans to the Cl anions, meanwhile, the thiophen part was not coordinated to Sn(IV) anymore. Moreover, only Cl…H H-bonds with nonclassical mononuclear and classical binuclear type of interactions were recorded. Computationally, the Cl…..H predominant interactions were confirmed by Hirschfeld Surface Analysis (HSA). TG of the complex was evaluated under open atmosphere. The complex's antifungal activity against the pathogenic Fusarium oxysporum f.sp. albedins (FOA) showed more activity compared by the free ligand. Furthermore, POM theory was applied to evaluate the bioactivity and explain the experimental result of desired material against fungal.
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