Substrate-independent fabrication of superhydrophilic membrane based on dopamine methacrylamide and zwitterionic substance for effective oil-in-water emulsion separation

乳状液 甲基丙烯酰胺 化学工程 超亲水性 材料科学 接触角 制作 基质(水族馆) 色谱法 化学 有机化学 共聚物 聚合物 病理 工程类 地质学 替代医学 海洋学 医学 生物化学 丙烯酰胺
作者
Cong Chen,Qiaohong Liu,Ziyun Yang,Qing Ye,Quan‐Fu An
出处
期刊:Journal of The Taiwan Institute of Chemical Engineers [Elsevier]
卷期号:139: 104513-104513 被引量:9
标识
DOI:10.1016/j.jtice.2022.104513
摘要

• The membrane for oil-water emulsion separation was fabricated by DMA deposition following MPC grafting. • The modification method developed was substrate-independent. • The modified membrane exhibited three times water flux of the pristine membranes. • The modified membranes demonstrated higher oil-in-water emulsion fluxes, enhanced oil rejection, and better anti-fouling performances. The fouling caused by oils and other contaminants is the critical obstacle for the membrane application in oil-in-water emulsion separation. To increase the hydrophilicity of the membrane, a substrate-independent approach was developed, in which the catechol derivative dopamine methacrylamide (DMA) was deposited on the membrane followed by UV copolymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC). Both hydrophobic membrane, poly(vinylidene fluoride), and hydrophilic membrane, polyethersulfone, became superhydrophilic after modification. The obtained membranes were characterized by Fourier-transform infrared spectroscopy (FTIR), Drop shape analyzer (DSA), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), and membrane pore-size analyzer. Additionally, pure water flux and oil-in-water emulsion separation performance were evaluated for the selected samples. The pure water flux of the modified membrane was increased from 490 L/m 2 h and 612 L/m 2 h to 1564 L/m 2 h and 2219 L/m 2 h under the optimal concentration of MPC for PVDF and PES membranes, respectively, which is more than three times that of the pristine membrane. Furthermore, the obtained membrane demonstrated enhanced oil-in-water emulsion separation efficiency as well as superior antifouling capabilities. The developed strategy is not restricted by the membrane materials, and might provide a new strategy for membrane surface modification aimed at oil-in-water emulsion separation.
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