材料科学
电磁屏蔽
图层(电子)
锌
离子
期限(时间)
纳米技术
化学工程
复合材料
有机化学
冶金
量子力学
物理
工程类
化学
作者
Jingchen Tao,Xinxin Cai,Yiran Li,Liang Huang,Xueying Zhang,Huiquan Zhang,Dongmin Ma,Ran Liang,Weixing Song
标识
DOI:10.1002/aenm.202403662
摘要
Abstract The zinc metal anodes are liable to experience detrimental dendrite growth and side reactions, thereby limiting the lifespan of aqueous Zn‐ion batteries. Here, a readily available supramolecule, dimethoxypillar[5]arene (DP[5]), is utilized as a shielding layer to stabilize the Zn anode by exploiting its zincophilicity derived from the ─OCH 3 functional groups and its hydrophobicity from the hydrophobic backbone. The DP[5] shielding layer regulates the solvation sheath of Zn 2+ and facilitates uniform zinc deposition. Swelling and dendrite formation are obviously suppressed in both the symmetric and full cells. The DP[5]‐Zn symmetrical cell cycles stably for 5500 h, and achieves a coulombic efficiency of 99.76% in a DP[5]‐Zn||Cu half‐cell after 2200 cycles. The DP[5]‐Zn||V 2 O 5 full cell maintains 92.03% of initial capacity after 6000 cycles. Given the cost‐effective fabrication and environmental friendliness of DP[5] films, this material may pave the way for practical applications of zinc anodes.
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