Magnetic biochar derived from macroalgal Sargassum hemiphyllum for highly efficient adsorption of Cu(II): Influencing factors and reusability

In this study, the brown algae Sargassum Hemiphyllum was used as a carbon source for synthesis of magnetic porous biochar via pyrolyzing at high temperature and and doping iron oxide particles (Fe-BAB). Cu (II) species were removed from aqueous solutions using Fe-BAB under various conditions. Fe-BAB demonstrated superior Cu (II) adsorption (105.3 mg g-1) compared to other biochars. On the surface of Fe-BAB, there are several oxygen-containing functional groups, such as -COOH and -OH, which are likely responsible for the excellent heavy metal removal performance. By utilizing magnet, the Fe-BAB can be conveniently separated from the solution and ready for further usage. Multi-adsorption mechanisms were responsible for Cu adsorption on Fe-BAB. Using the magnetic algal biochar for heavy metal removal is feasible due to its high adsorption efficiency and simplicity of separation.