催化作用
Atom(片上系统)
有机合成
同种类的
纳米技术
原子经济
均相催化
生化工程
组合化学
化学
材料科学
计算机科学
有机化学
物理
工程类
统计物理学
并行计算
作者
Wenhao Li,Jiarui Yang,Dingsheng Wang,Yadong Li
出处
期刊:Chem
[Elsevier]
日期:2022-01-01
卷期号:8 (1): 119-140
被引量:78
标识
DOI:10.1016/j.chempr.2021.10.030
摘要
In the history of synthesis, people applied heat, electricity, and other means to expand the synthesis field, thus promoting the construction of the magnificent material world. However, with the time passing, beyond the synthetic methods used in a laboratory, are there other solutions? The arising concept of single-atom catalysts (SACs) expands synthesis to the atomic scale. Through the fine-tuned and atom-level methods, people can obtain a catalytic scheme completely different from homogeneous catalysis, ultimately realizing the high-efficient, economical, and precise catalysis of synthesis. In this review, we focus on the latest development of synthesis involving SACs in the past 10 years. By discussing the reaction mechanism and combining the advantages of SACs, the structure-activity relationship is clarified, and the catalytic nature and general uses of SACs in the synthesis are summarized. Finally, we propose the opportunities, challenges, and development directions of SACs in organic synthesis in the next step.
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