碳化
超级电容器
材料科学
化学工程
比表面积
X射线光电子能谱
碳纤维
电解质
吸附
氢氧化钾
电化学
电极
有机化学
化学
复合材料
扫描电子显微镜
催化作用
物理化学
工程类
复合数
作者
Deqian Meng,Yunzhi Hu,Yidan Jing,Xiaomin Zhang,Sakil Mahmud,Shengpei Su,Jin Zhu
出处
期刊:Fuel
[Elsevier]
日期:2022-03-30
卷期号:320: 124002-124002
被引量:35
标识
DOI:10.1016/j.fuel.2022.124002
摘要
Biomass-derived porous carbon materials were widely used in the preparation of supercapacitors due to their excellent electrical conductivity and large specific surface area. However, much research on the preparation process still involved pre-carbonization and high-temperature cracking. The preparation process was complicated and energy-consuming, which largely limited the development of biomass-based supercapacitors. Here, the chitosan gel was first obtained by a freeze-dried method, and then it was immersed into potassium hydroxide (KOH) solution and got the carbon precursor. Finally, a simple one-step carbonization process successfully prepared its hierarchical N-doped porous carbon (NPC) material. The N2 isothermal adsorption–desorption test and X-ray photoelectron spectroscopy (XPS) analysis showed the prepared NPC material had a specific surface area of 2787.47 m2 g−1 and an N content of 4.68 %. The electrochemical performance test showed that the prepared NPC material had a specific capacitance of 253F g−1 (0.5 A g−1) in 6 M KOH electrolyte under the three-electrode system. When assembled as an asymmetrical supercapacitor, the energy density was 5.83 Wh kg−1 at a power density of 4997.1 W kg−1 in a 6 M KOH electrolyte. Particularly, this study provided a simple strategy for synthesizing NPC materials with excellent properties.
科研通智能强力驱动
Strongly Powered by AbleSci AI