卡诺循环
均分定理
热效率
高效能源利用
统计物理学
工作(物理)
热机
谐振子
量子
数学
可用能
物理
热力学
量子力学
火用
工程类
化学
有机化学
磁场
电气工程
燃烧
作者
Zhaoyu Fei,Jin-Fu Chen,Yuhan Ma
出处
期刊:Physical review
日期:2022-02-16
卷期号:105 (2)
被引量:16
标识
DOI:10.1103/physreva.105.022609
摘要
The stochastic efficiency [G. Verley et al., Nat. Commun. 5, 4721 (2014)] was introduced to evaluate the performance of energy-conversion machines in micro-scale. However, such an efficiency generally diverges when no heat is absorbed while work is produced in a thermodynamic cycle. As a result, any statistical moments of the efficiency do not exist. In this study, we come up with a different version of the definition for the stochastic efficiency which is always finite. Its mean value is equal to the conventional efficiency, and higher moments characterize the fluctuations of the cycle. In addition, the fluctuation theorems are re-expressed via the efficiency. For working substance satisfying the equipartition theorem, we clarify that the thermodynamic uncertainty relation for efficiency is valid in an Otto engine. To demonstrate our general discussions, the efficiency statistics of a quantum harmonic-oscillator Otto engine is systematically investigated. The probability that the stochastic efficiency surpasses the Carnot efficiency is explicitly obtained. This work may shed new insight for optimizing micro-machines with fluctuations.
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