Introducing Postmetalation Metal–Organic Framework to Control Perovskite Crystal Growth for Efficient Perovskite Solar Cells

A novel lead-containing metal-organic framework (Pb-MOF) is synthesized through postmetalation of MOF-525. Postmetalation renders lead ions bound with the organic linker of MOF-525, which can serve as nucleation points to promote perovskite crystallization. The introduction of lead postmetalated MOF-525 (Pb-MOF) as a scaffold layer between compact TiO2 (c-TiO2) layer and perovskite layer promotes perovskite crystal growth in enlarging crystal grain size with better crystallinity, hence decreasing defect sites in the perovskite layer. Postmetalation of MOF-525 with lead ions allows MAPbI3 to form a solid crystal structure to facilitate the charge separation between electron transport layer (ETL) and light-harvesting layer so as to resolve the issue of possible vacancies present in MOFs. As a result, the champion perovskite solar cell (PSC) with the introduction of Pb-MOF exhibits a power conversion efficiency (PCE) of 20.87% and better stability (86% PCE retention after 40 days), outperforming the pristine PSC (16.85% PCE, with 52% retention after 40 days) and MOF-525-introduced PSC (18.61% PCE, with 76% retention after 40 days).