三碘化物
化学
催化作用
钒
电化学
铂金
能量转换效率
辅助电极
无机化学
锰
化学工程
电子转移
色素敏化染料
纳米技术
电极
电解质
光化学
光电子学
材料科学
物理化学
有机化学
工程类
作者
Yunjiang Li,Xueying Xu,Ting Wang,Tuo Ji,Fengrui Li,Weilin Chen,Lu Ding
标识
DOI:10.1021/acs.inorgchem.1c03080
摘要
The rational design of efficient triiodide reduction reaction catalysts that are dependent on cheap and ample elements on Earth has become a challenge. As an extremely encouraging non-noble metallic catalyst, MoS2 requires effective strategies to improve the site accessibility, inherent conductivity, and structural stability. Here, vanadium-substituted Keggin-type polyoxometalates (POMs) can be used as electron aggregates to modify manganese (Mn)-doped MoS2 through the electrochemical deposition strategy, thereby improving the charge transfer ability of MoS2 to I-/I3- redox pairs and accelerating the reduction of I3-. Additionally, with the increase in the number of vanadium atoms substituted in POMs, the conduction band of POMs and MoS2 can also match better, which effectively reduces the energy loss and is more conducive to charge transfer. Meanwhile, the deposition of POMs can improve the stability of metastable MoS2. When POMs/MoS2 materials are used as the counter electrodes of dye-sensitized solar cells, the power conversion efficiency (PCE) obtained is 7.27%, which is higher than that of platinum (Pt) (6.07%). The PCE can still maintain the initial 96% after 9 days. This work provides a valuable way for the improvement of platinum-free catalysts with minimal expense, basic process, high efficiency, and good stability.
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