化学计量学
芳樟醇
化学
单萜
萜烯
环糊精
双环分子
包合物
有机化学
立体化学
精油
色谱法
标识
DOI:10.1016/j.cplett.2016.03.051
摘要
The crystal structures of the complexes of β-cyclodextrin with two chiral terpene alcohols are presented. (−)-Linalool forms the complex of a 2:2 host–guest stoichiometry, while the complex with (−)-isopinocampheol exhibits a 2:3 stoichiometry. The comparison of the crystal structures with the data for other complexes of β-cyclodextrin with chiral monoterpene alcohols obtained from Cambridge Structural Database (CSD) highlights the tendency of linear and monocyclic alcohols to form complexes of 2:2 stoichiometry whereas bicyclic alcohols prefer to form 2:3 host–guest inclusion complexes.
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