热液循环
钛酸钡
溶解
粒径
杂质
水热合成
氢氧化钡
钛酸酯
矿物学
材料科学
化学工程
降水
相(物质)
化学
无机化学
分析化学(期刊)
物理化学
陶瓷
冶金
色谱法
有机化学
物理
气象学
工程类
作者
Jung hoon Park,Sang do Park
出处
期刊:Journal of Chemical Engineering of Japan
[The Society of Chemical Engineers Japan]
日期:2008-01-01
卷期号:41 (7): 631-638
被引量:8
摘要
The formation of nano-sized barium titanate powders by hydrothermal reaction between barium hydroxide octahydrate and hydrous titania was studied at various temperatures, times and reactant concentrations without mineralizer. FTIR, TGA, SEM, XRF, BET and XRD were used to investigate the effects of temperature, time and concentration on reactivity, particle size, morphology and secondary phase of BaTiO3 powder prepared hydrothermally. The main impurities were BaCO3, TiO2, surface H2O and lattice OH– radical at low conversion while secondary phase such as the lattice hydroxyl radical and trace BaCO3 remained at high conversion. As the temperature and time increased in low concentration reaction below 0.5 M, the maximum conversion could not exceed 98% but the conversion increased with increasing concentration, reaching over 99% above 1.5 M. In addition, concentration of more than 1.5 M was favorable to smaller particle size, better sphericity and Ba/Ti ratio ≒ 1. Kinetic analysis by the Johnson–Mehl–Avrami plot shows hydrothermal reaction progresses through solidification path. Initially, dissolution-precipitation mechanism takes place to form the nuclei of BaTiO3 through fast dissolution of TiO2·xH2O and reaction with Ba2+ ions and then the BaTiO3 crystal begins to grow.
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