Boosting visible-light photocatalytic performance of g-C3N4/Fe3O4 anchored with CoMoO4 nanoparticles: Novel magnetically recoverable photocatalysts

光催化 高分辨率透射电子显微镜 煅烧 纳米复合材料 材料科学 X射线光电子能谱 化学 化学工程 三元运算 纳米颗粒 可见光谱 纳米技术 核化学 催化作用 透射电子显微镜 光电子学 有机化学 工程类 计算机科学 程序设计语言
作者
Aziz Habibi‐Yangjeh,Mitra Mousavi,Kazuya Nakata
出处
期刊:Journal of Photochemistry and Photobiology A-chemistry [Elsevier BV]
卷期号:368: 120-136 被引量:163
标识
DOI:10.1016/j.jphotochem.2018.09.026
摘要

Abstract In the present work, visible-light-driven g-C3N4/Fe3O4/CoMoO4 photocatalysts (denoted as CN/FeO/CoMoO4) were fabricated by a refluxing-calcination route. The phase, morphology, composition, texture, structure, electronic, textural, thermal, and magnetic properties of the fabricated nanocomposites were studied by XRD, EDX, SEM, TEM, HRTEM, XPS, FT-IR, UV–vis DRS, PL, BET, TGA, and VSM instruments. When the weight percentage of CoMoO4 was 30%, photocatalytic performance of the ternary nanocomposite in degradations of RhB, MB, MO, fuchsine, and photoreduction of Cr(VI) was almost 10, 15, 31.8, 37, and 23.2 times higher than that achieved by the pure g-C3N4. This substantially improved photocatalytic performance was attributed to more production of charge carriers, efficient separation of them from recombination, and enhanced textural properties. Moreover, the photocatalyst was magnetically recovered with negligible loss in the activity, which has key role in design of the sustainable photocatalysts. Therefore, the CN/FeO/CoMoO4 photocatalysts could have potential applications in the environmental remediations.

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