An Efficient Synthesis of Isomeric 1‐(1‐Alkyl‐1H‐pyrazolyl) Ethanones

A simple and versatile general method for the preparation of N ‐substituted 3‐, 4‐, or 5‐acetylpyrazoles from corresponding acids via hydrolysis and decarboxylation of substituted diethyl [(1‐alkyl‐1 H ‐pyrazolyl)carbonyl]malonates was developed. Title compounds were prepared in three steps without isolation of intermediates in 48–82% overall yield.