环己烷
乙醚
化学
甲苯
热力学
绝对偏差
乙醚
分析化学(期刊)
色谱法
有机化学
数学
统计
物理
作者
Fei Yu,Liu‐Ying Yu,Ke‐Jun Wu,Chao‐Hong He
标识
DOI:10.1021/acs.jced.1c00132
摘要
In this work, the thermal conductivities of toluene, cyclohexane, and diethyl ether were measured from 291 to 351 K at pressures up to 15.1 MPa. The binary systems of toluene–cyclohexane, toluene–diethyl ether, and cyclohexane–diethyl ether were also measured from 291 to 351 K at pressures 0.1 and 10.1 MPa. The relative expanded uncertainty of the obtained data was estimated to be ±2% with a confidence level of 0.95 (k = 2). The linear thermal conductivity model was used to correlate the pure components as a function of temperature and pressure. The thermal conductivities of binary systems were fitted as a function of temperature and composition. For pure components, the maximum values of absolute percentage deviation (AAD) and maximum absolute percentage deviation (MAD) are 0.45 and 0.87%, respectively. For binary systems, the maximum values of AAD and MAD are 0.56 and 1.79%, respectively.
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