Evaluation of metal-supported solid oxide fuel cells (MS-SOFCs) fabricated at low temperature (∼1,000 °C) using wet chemical coating processes and a catalyst wet impregnation method

催化作用 氧化物 材料科学 电解质 化学工程 涂层 电化学 氧化剂 固体氧化物燃料电池 冶金 化学 纳米技术 物理化学 有机化学 阳极 工程类 生物化学 电极
作者
Kun Ho Lee,Jong-Ho Kang,Jaeseok Lee,Sang-Hun Lee,Joongmyeon Bae
出处
期刊:International Journal of Hydrogen Energy [Elsevier]
卷期号:43 (7): 3786-3796 被引量:28
标识
DOI:10.1016/j.ijhydene.2018.01.027
摘要

The objective of this study is to evaluate metal-supported solid oxide fuel cells fabricated at low temperatures (∼1000 °C) in oxidizing environments using wet chemical coating processes and a catalyst impregnation method. Typically, applying general wet chemical coating processes and heat treatment at low temperature is desirable for fabricating metal-supported solid oxide fuel cells when considering manufacturing productivity and efficiency. However, in the case of conventional anodes, a well-organized structure for high performance is rarely formed by sintering at low temperatures when using general fabrication processes. For this reason, a catalyst-impregnated anode is designed and applied to overcome the above issue. First, to evaluate the electrochemical performance of the designed anode, the area-specific resistances of half-cells are investigated. Then, the newly designed anode is applied to a single cell, and microstructural analysis and electrochemical performance measurements are performed. These results confirm that the catalysts are well distributed, that the electrolyte is fully dense and that the electrochemical performances are reasonable. Additionally, the high durability is also verified through a long-term test over 1000 h. Finally, the metal-supported solid oxide fuel cell with a catalyst-impregnated anode fabricated at low temperature is completely validated through the evaluation of a large-size single cell.
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