Visible‐Light‐Promoted Synthesis of 1,4‐Dicarbonyl Compounds via Conjugate Addition of Aroyl Chlorides

Abstract A facile visible‐light photocatalytic conjugate addition to prepare 1,4‐dicarbonyl compounds has been developed by employing readily available aroyl chlorides as aryl radical sources. This operationally simple method shows a broad scope with regard to both aroyl chlorides and Michael acceptors. As a result, a variety of 1,4‐diketones were efficiently synthesized in moderate to good yields.