Bio-inspired, bimetal ZIF-derived hollow carbon/MXene microstructure aim for superior microwave absorption

Electromagnetic pollution has become an increasingly important problem which has drawbacks to both the accurate operation of the electronic facilities and the safety of human beings. To alleviate and eliminate electromagnetic irradiation, it is inevitable to design microwave absorption materials with desirable absorption intensity and broad effective frequency bandwidth. The combination of carbon-based materials and magnetic materials is an adoptable strategy to perform remarkable microwave absorption performance, while the microstructure should not be ignored. Inspired by the electromagnetic response behaviors of the microstructure from the leafhopper, the hetero-microstructure with hollow void is constructed by adopting bimetal ZIF as the precursor, followed by an interfacial tailoring strategy through electrostatic assembling and calcinating process, which enhances the microwave absorption performance by integrating the merits between the components and the micro-structure. The minimum value of reflection loss achieved -76.40 dB at 7.50 GHz under filler loading of 20% with the thickness of 2.92 mm. Besides, the effective absorption bandwidth could be tailored from 3.55 to 18 GHz among different thicknesses as required. The bio-inspired strategy is validated as a promising method, exhibiting great potential in the designing of the next-generation microwave absorber.