Modulating the Oxidation State of Titanium via Dual Anions Substitution for Efficient N2 Electroreduction

Abstract The electrocatalytic nitrogen reduction reaction (NRR) is a promising approach for renewable ammonia synthesis but remains significantly challenging due to the low yield and poor selectivity. Herein, a facile N and S dual anions substitution strategy is developed to tune the Ti oxidation states of TiO 2 nanohybrid catalyst (NS‐TiO 2 /C), in which anatase TiO 2 nanoplates with dense Ti 3+ active sites are uniformly dispersed on porous carbon derived from 2D Ti 3 C 2 T x nanosheets. The catalyst NS‐TiO 2 /C exhibits a superior ambient NRR efficiency with an NH 3 yield rate of 19.97 µg h −1 mg −1 cat and Faradaic efficiency of 25.49% and is coupled with a remarkable 50 h long‐term stability at − 0.25 V versus RHE. Both experimental and theoretical results reveal that the N and S dual‐substitution effectively regulate the Ti oxidation state and electronical properties of the NS‐TiO 2 /C via simultaneously forming interstitial and substitutional TiS and TiN bonds in the anatase TiO 2 lattice, inducing oxygen vacancies and dense Ti 3+ active species as well as better electronic conductivity, which substantially facilitates N 2 chemisorption and activation, and reduces the energy barrier of the rate‐determining step, thereby essentially boosting NRR efficiency. This work provides a valuable approach to the rational design of advanced materials by modulating oxidation states for efficient electrocatalysis.