法拉第效率
硫黄
材料科学
锂(药物)
吸附
阴极
化学工程
纳米技术
化学
电化学
电极
冶金
有机化学
物理化学
工程类
内分泌学
医学
作者
Xiaochuan Chen,Libo Li,Yuhang Shan,Da Zhou,Wenjun Cui,Yangmingyue Zhao
标识
DOI:10.1016/j.jechem.2022.02.046
摘要
Limited by the shuttle effect, the application of lithium-sulfur batteries is not impressive. As an organ layered two-dimensional (2D) material, MXene has a great electrical conductivity and high specific surface area. Meanwhile, the introduction of metal oxides can restrain the shuttle effect. Hence, this paper prepared CeO2/MXene as a cathode material of Li-S batteries. Ce and Ti can chemically adsorb S, and the interlayer structure of MXene can limit S while the interlayer space can alleviate volume expansion. The discharge capacity at 0.5 C is as high as 1051.1 mAh g−1, and 921.9 mAh g−1 after 200 cycles. The average coulombic efficiency is 97.75%. The organized MXene with CeO2 like notes in accordions are new efficient materials for lithium-sulfur batteries.
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