腐蚀
合金
材料科学
冶金
6111铝合金
相(物质)
电化学
电极
化学
物理化学
有机化学
作者
Rui Wang,Dongtao Wang,Hiromi Nagaumi,Zibin Wu,Xiaozu Zhang,Xinzhong Li
标识
DOI:10.1016/j.matlet.2022.131658
摘要
• Proper Zn addition improves the corrosion resistance of as-cast Al-Si-Cu alloy. • Excessive Zn addition enhances the tendency of Si phase as a cathode. • Adding ~1% Zn to Al-6Si-3Cu alloy reduces the corrosion rate by 19.8%. In order to improve the corrosion resistance of as-cast Al-Si-Cu alloy, in this work, the effects of Zn content are investigated by using SEM, EDS and electrochemical studies. The results show that with Zn content increasing, the corrosion resistance of Al-6Si-3Cu alloy first becomes stronger and then weaker. The alloy with 0.97 wt% Zn exhibits the best corrosion resistance. Its corrosion rate is lower than that of Al-6Si-3Cu alloy. The addition of Zn produces a Zn-rich area around Al 2 Cu phase and weakens the corrosion process between Al 2 Cu phase and Al matrix. However, excessive Zn addition changes the morphology of Al 2 Cu phase and makes it act as electron transfer channel between Si phase, which shows a negative effect on corrosion resistance.
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