催化作用
共价键
分子
化学
分子工程
组合化学
合理设计
金属
联吡啶
吸附
反应性(心理学)
纳米技术
材料科学
有机化学
晶体结构
病理
替代医学
医学
作者
Zhi‐Wen Yang,Jinmei Chen,Liqi Qiu,Wen‐Jun Xie,Liang‐Nian He
标识
DOI:10.1002/anie.202205301
摘要
The electrocatalytic CO2 reduction reaction (ECO2 RR) is one promising method for storing intermittent clean energy in chemical bonds and producing fuels. Among various kinds of catalysts for ECO2 RR, molecular metal complexes with well-defined structures are convenient for studies of their rational design, structure-reactivity relationships, and mechanisms. In this Review, we summarize the molecular engineering of several N-based metal complexes including Re/Mn bipyridine compounds and metal macrocycles, concluding with general modification strategies to devise novel molecular catalysts with high intrinsic activity. Through physical adsorption, covalent linking, and formation of a periodic backbone, these active molecules can be heterogenized into immobilized catalysts with more practical prospects. Finally, significant challenges and opportunities based on molecular catalysts are discussed.
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