Multi‐Emission from Single Metal–Organic Frameworks under Single Excitation

Multi-emission materials have come to prominent attention ascribed to their extended applications other than single-emission ones. General and robust design strategies of a single matrix with multi-emission under single excitation are urgently required. Metal-organic frameworks (MOFs) are porous materials prepared with organic ligands and metal nodes. The variety of metal nodes and ligands makes MOFs with great superiority as multi-emission matrices. Guest species encapsulated into the channels or pores of MOFs are the additional emission sites for multi-emission. In this review, multi-emission MOFs according to the different excitation sites are summarized and classified. The emission mechanisms are discussed, such as antenna effect, excited-state intramolecular proton transfer (ESIPT) and tautomerism for dual-emission. The factors that affect the emissions are revealed, including ligand-metal energy transfer and host-guest interaction, etc. Multi-emission MOFs could be predictably designed and prepared, once the emissive factors are controlled rationally in combination with the different multi-emission mechanisms. Correspondingly, new and practical applications are realized, including but not limited to ratiometric/multi-target sensing and bioimaging, white light-emitting diodes, and anti-counterfeiting. The design strategies of multi-emission MOFs and their extensive applications are reviewed. The results will shed light on other multi-emission systems to develop the structure-derived functionality and applications.