分馏
分数(化学)
萃取(化学)
有机质
碳酸盐
傅里叶变换红外光谱
环境科学
环境化学
化学
金属
污水
环境工程
色谱法
量子力学
物理
有机化学
作者
Magdalena Sut‐Lohmann,Shaghayegh Ramezany,Friederike Kästner,Thomas Raab,Martina Heinrich,Mark Grimm
标识
DOI:10.1016/j.jenvman.2021.114229
摘要
The main objectives of this study were to evaluate the Cu, Zn, Pb, Cr and Ni mobility using modified Tessier sequential extraction procedure and to study the functional group changes affected by each extraction step using FTIR analysis in the soil of a former sewage farm sedimentation basin. Tessier extraction revealed element dependent fractionation of studied metals: Pb was mostly discovered in the residual fraction (77%) followed by Cr (53%), Cu (8%), and Zn (5%), while Ni was not extracted in this fraction. The organic matter-bound was the dominant species of Cu (77%). Zn and Ni exhibited the highest affinity for Fe/Mn oxides fraction (55% and 39%, respectively). The average recovery rate was 62-111%, whereas the lowest rate was obtained for Ni (62%) and the highest for Cu/Pb (110-111%). Results indicated elevated concentrations of studied elements, with the following order of mobility factor: Ni > Zn > Cu > PbCr. The preliminary interpretation of the sequential extraction FTIR spectral response revealed that DRIFT is applicable to interpret the sequential metal extraction and revealed three most profound changes correlated to the carbonate, Fe/Mn oxides, and OM fraction.
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