化学
西格玛反应
重排反应
反应条件
基质(水族馆)
组合化学
光化学
立体化学
有机化学
催化作用
海洋学
地质学
作者
Yuerong Wang,Pengfei Jia,Yingdi Hao,Jianglian Li,Ruizhi Lai,Li Guo,Yong Wu
标识
DOI:10.1016/j.tetlet.2022.154098
摘要
Metal-free blue light-mediated [2,3]-sigmatropic rearrangement reactions of tosylhydrazones and sulfides are reported herein. This strategy shows great enhancement compared to the traditional methods because of stable starting materials and mild reaction conditions. In this report, we have developed the Doyle-Kirmse reaction and Sommelet-Hauser reaction with simple operation, high yields and broad substrate adaptability. Metal-free blue light-mediated [2,3]-sigmatropic rearrangement reactions of tosylhydrazones and sulfides are reported herein. This strategy shows great enhancement compared to the traditional methods because of stable starting materials and mild reaction conditions. In this report, we have developed the Doyle-Kirmse reaction and Sommelet-Hauser reaction with simple operation, high yields and broad substrate adaptability.
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