Peracetic acid as an alternative disinfectant for micropollutants degradation and disinfection byproducts control in outdoor swimming pools

Peracetic acid (PAA) has garnered significant interest as a novel alternative to chlorine-based disinfectants for water treatment due to its broad-spectrum antimicrobial activity and its ability of reactive species generation when exposed to UV light. However, limited studies have investigated micropollutant degradation in the presence of PAA under solar irradiation. This is the first study to comprehensively investigate the photodegradation of caffeine (CAF) and 4-methylbenzylidene camphor (4-MBC) and the removal of disinfection byproducts (DBPs) in the presence of PAA under simulated solar light. The study revealed that the photodegradation of CAF and 4-MBC was significantly enhanced in the presence of PAA, following pseudo-first-order kinetics (R2 > 0.98) with reaction rates (kobs) of 0.220 and 0.111 h-1, respectively. In addition, substantial reduction of 21 DBPs, including trihalomethanes, haloacetic acids and haloacetonitriles, and no DBPs formation were observed in the presence of PAA and simulated solar irradiation. The proportion of coexisting H2O2 in the PAA solution considerably influenced target compounds degradation. CAF and 4-MBC were degraded faster under acidic conditions than under alkaline conditions. Hydroxyl radicals (·OH) dominated the degradation of CAF at different pH values, while direct photolysis and other reactive species played a major role in the degradation of 4-MBC. Swimming pools commonly use chlorine-based disinfectants, resulting in a significant production of disinfection byproducts (DBPs). While a few European countries only regulate trihalomethanes in pool water, it is vital to introduce alternative disinfectants in order to reduce the formation of harmful DBPs and ensure a safer swimming environment. Existing literature of peracetic acid (PAA) has mainly focused on disinfection performance in water treatment, with no studies has been conducted in swimming pools. This study provides encouraging findings on the potential and feasibility of using PAA to degrade emerging organic micropollutants and control DBPs in swimming pools under solar irradiation.