Trion Photoluminescence and Trion Stability in Atomically Thin Semiconductors

The optical response of doped monolayer semiconductors is governed by trions, i.e. photoexcited electron-hole pairs bound to doping charges. While their photoluminescence (PL) signatures have been identified in experiments, a microscopic model consistently capturing bright and dark trion peaks is still lacking. In this work, we derive a generalized trion PL formula on a quantum-mechanical footing, considering direct and phonon-assisted recombination mechanisms. We show the trion energy landscape in ${\mathrm{WSe}}_{2}$ by solving the trion Schr\"odinger equation. We reveal that the mass imbalance between equal charges results in less stable trions exhibiting a small binding energy and, interestingly, a large energetic offset from exciton peaks in PL spectra. Furthermore, we compute the temperature-dependent PL spectra for $n$- and $p$-doped monolayers and predict yet unobserved signatures originating from trions with an electron at the $\mathrm{\ensuremath{\Lambda}}$ point. Our work presents an important step toward a microscopic understanding of the internal structure of trions determining their stability and optical fingerprint.