Fabrication and Characterization of Carbon Nanotube Filled PDMS Hybrid Membranes for Enhanced Ethanol Recovery

Ethanol separation via the pervaporation process has shown growing application potential in solvent recovery and the bioethanol industry. In the continuous pervaporation process, polymeric membranes such as hydrophobic polydimethylsiloxane (PDMS) have been developed to enrich/separate ethanol from dilute aqueous solutions. However, its practical application remains largely limited due to the relatively low separation efficiency, especially in selectivity. In view of this, hydrophobic carbon nanotube (CNT) filled PDMS mixed matrix membranes (MMMs) aimed at high-efficiency ethanol recovery were fabricated in this work. The filler K-MWCNTs was prepared by functionalizing MWCNT-NH2 with epoxy-containing silane coupling agent (KH560) to improve the affinity between fillers and PDMS matrix. With K-MWCNT loading increased from 1 wt % to 10 wt %, membranes showed higher surface roughness and water contact angle was improved from 115° to 130°. The swelling degree of K-MWCNT/PDMS MMMs (2 wt %) in water were also reduced from 10 wt % to 2.5 wt %. Pervaporation performance for K-MWCNT/PDMS MMMs under varied feed concentrations and temperatures were evaluated. The results supported that the K-MWCNT/PDMS MMMs at 2 wt % K-MWCNT loading showed the optimum separation performance (compared with pure PDMS membranes), with the separation factor improved from 9.1 to 10.4, and the permeate flux increased by 50% (40-60 °C, at 6 wt % feed ethanol concentration). This work provides a promising method for preparing a PDMS composite with both high permeate flux and selectivity, which showed great potential for bioethanol production and alcohol separation in industry.