A Revisit of Crystallization in Tin Halide Perovskite Thin Films: From Nucleation, Intermediate to Crystal Growth

材料科学 成核 结晶 卤化物 晶体生长 钙钛矿(结构) Crystal(编程语言) 薄膜 结晶学 化学工程 纳米技术 无机化学 冶金 有机化学 化学 计算机科学 程序设计语言 工程类
作者
Mingyu Yin,Huanhuan Yao,Hongju Qiu,Cheng Wu,Miao Zhang,Feng Hao
出处
期刊:Advanced Functional Materials [Wiley]
被引量:1
标识
DOI:10.1002/adfm.202404792
摘要

Abstract Perovskite solar cells (PSCs) are exuding unique charm in the third generation of thin film solar cell technology with high power conversion efficiency (PCE) and low production cost. Recently, the lead‐free tin halide perovskite solar cells (TPSCs) have drawn significant research interests due to the advantages of low toxicity, near‐ideal bandgap and high carrier mobility. However, the rapid crystallization and easy oxidation limits the film quality and final performance of the solar cells. Therefore, the deposition of high‐quality tin halide perovskite films is key to the advance of TPSCs. In this review, the classical theory of solution nucleation and crystal growth is reviewed and correlated to the practical deposition of tin perovskite film. The physicochemical properties of tin perovskite with those of lead counterpart and the differences in the crystallization process is carefully compared. On this basis, recent regulation strategies are systematically summarized in terms of the nucleation management, intermediate phase engineering and crystal growth regulation. In addition, the preparation of mixed tin‐lead (Sn‐Pb) PSCs toward high performance is also discussed, as well as the limiting factors for device performance and stability. Finally, the future challenges and prospects of the crystallization regulation are discussed toward more efficient and stable TPSCs.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
1秒前
2秒前
3秒前
caikeke发布了新的文献求助10
3秒前
Ting发布了新的文献求助10
3秒前
4秒前
上官若男应助hxd采纳,获得10
4秒前
4秒前
AppleDog发布了新的文献求助10
6秒前
7秒前
Yjh发布了新的文献求助10
7秒前
谦让夜香完成签到,获得积分10
9秒前
Cat应助胡豆豆采纳,获得30
10秒前
10秒前
13秒前
耍酷千山发布了新的文献求助10
13秒前
一碗鱼发布了新的文献求助10
14秒前
min17完成签到,获得积分10
14秒前
AppleDog完成签到,获得积分10
15秒前
goodesBright应助wwwchhh采纳,获得10
15秒前
夏果果发布了新的文献求助10
15秒前
追寻紫安应助狂野的念波采纳,获得10
15秒前
16秒前
16秒前
何哈哈完成签到,获得积分10
17秒前
Yvonne发布了新的文献求助10
18秒前
19秒前
平淡问雁发布了新的文献求助10
20秒前
20秒前
20秒前
CipherSage应助kaneki采纳,获得10
21秒前
21秒前
积德行善SCI无边完成签到,获得积分0
21秒前
今后应助夏果果采纳,获得10
22秒前
生椰拿铁不加生椰完成签到 ,获得积分10
23秒前
24秒前
小虫发布了新的文献求助10
25秒前
周慧玲完成签到 ,获得积分10
25秒前
专注的草丛完成签到,获得积分10
26秒前
26秒前
高分求助中
Sustainability in Tides Chemistry 1500
TM 5-855-1(Fundamentals of protective design for conventional weapons) 1000
CLSI EP47 Evaluation of Reagent Carryover Effects on Test Results, 1st Edition 800
Threaded Harmony: A Sustainable Approach to Fashion 799
Livre et militantisme : La Cité éditeur 1958-1967 500
Retention of title in secured transactions law from a creditor's perspective: A comparative analysis of selected (non-)functional approaches 500
"Sixth plenary session of the Eighth Central Committee of the Communist Party of China" 400
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3055485
求助须知:如何正确求助?哪些是违规求助? 2712292
关于积分的说明 7430453
捐赠科研通 2357116
什么是DOI,文献DOI怎么找? 1248604
科研通“疑难数据库(出版商)”最低求助积分说明 606750
版权声明 596093