普鲁士蓝
电催化剂
钴
锌
兴奋剂
电池(电)
氧气
碳纤维
无机化学
化学
析氧
联轴节(管道)
材料科学
电极
电化学
光电子学
冶金
有机化学
物理化学
物理
复合数
功率(物理)
量子力学
复合材料
作者
Wendi Dang,Lingling Miao,Na Zhao,Ximing Deng,Lingwei Zhang,Wei Wang
标识
DOI:10.1016/j.diamond.2024.111326
摘要
Recently, CoP is considered as a very promising electrode material for rechargeable zinc-air battery (ZAB). In this study, a Prussian blue analogue (Co3[Co(CN)6]2, PBA) derived CoP coupling with N-doped carbon (NC) as an effective oxygen electrocatalyst PBA-CoP/NC was prepared. Notably, as-prepared PBA-CoP/NC has good oxygen reduction reaction (ORR) performance even comparable to Pt/C (0.855 V), with half wave potential reaching 0.847 V. While, it also has satisfactory performance for oxygen evolution reaction (OER). Importantly, the PBA-CoP/NC assembled ZAB exhibits an open circuit potential of 1.62 V, and a peak power density of 119.3 mW cm−2, as well as good stability. This PBA-CoP/NC catalyst would give good reference to developing advanced carbon-based electrocatalyst, also has great potential applied in other energy storage devices.
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