材料科学
陶瓷
微波食品加热
电介质
晶体结构
化学键
Crystal(编程语言)
介电损耗
矿物学
结晶学
复合材料
光电子学
有机化学
化学
计算机科学
程序设计语言
物理
量子力学
作者
Zegui Hou,Yingxiang Li,Fei Wang,Deyin Liang,Bin Tang,Wei Liu,Chuansheng He,Zixuan Fang,Zitao Shi,Jingjing Chen,Qi Xu,Hao Li
标识
DOI:10.1016/j.ceramint.2024.09.006
摘要
Ceramics of Li2Mg2GaTi2O8F (LMGTOF) were prepared by the traditional solid-state method. XRD and TEM results confirmed that a single phase of Li2Mg2GaTi2O8F, with an Fd-3m space group and a cubic spinel structure, was formed by the ceramics. It was shown by the results that the lattice parameters of the ceramics at 1050 °C were measured as a = b = c = 8.36576 Å, with a volume of V = 585.485549 Å3. Furthermore, it was observed through the analysis of the Raman peak at 718 cm−1 that an inverse relationship was exhibited between the Raman shift and εr. Similarly, an opposing trend was also demonstrated between the Q × f value and FWHM. By bond valence analysis, it was shown that Mg2+, Ga3+, and Ti4+ ions were in a "rattling" state, and the large positive deviation between εcorr and εtheo was attributed to the strong "rattling" effect induced by the cations. At 1050 °C, the best microwave dielectric properties (εr = 14.58, Q × f = 76,689 GHz, and τf = −52 ppm/°C) were exhibited by LMGTOF ceramics.
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