Strategy in Promoting Visible Light Absorption, Charge Separation, CO2 Adsorption and Proton Production for Efficient Photocatalytic CO2 Reduction with H2O

Abstract Solar‐energy‐driven photocatalytic CO 2 reduction by H 2 O to high‐valuable carbon‐containing chemicals has become one of the greatest concerns in both scientific and industrial communities, due to its potential in solving energy and environmental problems. However, efficiency of photocatalytic CO 2 reduction by H 2 O is still far below the needs of large‐scale applications. The reduction efficiency is closely related to ability of photocatalysts in absorbing visible light which is the main part of sunlight (44 %), separating photogenerated electron‐hole pairs, adsorbing CO 2 and producing protons for reducing CO 2 . Thus, photocatalysts with enhanced visible light absorption, electron‐hole separation, CO 2 adsorption and proton production are highly desired. Herein, we aim to provide a picture of recent progresses in improving ability of photocatalysts in visible light absorption, electron‐hole separation, CO 2 adsorption and proton production, and give an outlook for future researches associated with photocatalytic CO 2 reduction by H 2 O.