木质素
环氧化大豆油
乳酸
食品包装
复合数
甲基丙烯酸酯
材料科学
大豆油
高分子化学
化学工程
复合材料
有机化学
化学
聚合物
食品科学
共聚物
细菌
原材料
生物
遗传学
工程类
作者
Yingxin Zhou,Kang Shi,Guoshuai Liu,Hui Sun,Yunxuan Weng
出处
期刊:Polymers
[MDPI AG]
日期:2024-07-16
卷期号:16 (14): 2025-2025
标识
DOI:10.3390/polym16142025
摘要
The application of lignin as a filler for poly (lactic acid) (PLA) is limited by their poor interfacial adhesion. To address this challenge, lignin-graft-poly(lauryl methacrylate) (LG-g-PLMA) was first blended with poly (lactic acid), and then epoxidized soybean oil (ESO) was also added to prepare PLA/LG-g-PLMA/ESO composite, which was subsequently hot pressed to prepare the composite films. The effect of ESO as a plasticizer on the thermal, mechanical, and rheological properties, as well as the fracture surface morphology of the PLA/LG-g-PLMA composite films, were investigated. It was found that the compatibility and toughness of the composites were improved by the addition of ESO. The elongation at break of the composites with an ESO content of 5 phr was increased from 5.6% to 104.6%, and the tensile toughness was increased from 4.1 MJ/m3 to 44.7 MJ/m3, as compared with the PLA/LG-g-PLMA composite without ESO addition. The toughening effect of ESO on composites is generally attributed to the plasticization effect of ESO, and the interaction between the epoxy groups of ESO and the terminal carboxyl groups of PLA. Furthermore, PLA/LG-g-PLMA/ESO composite films exhibited excellent UV barrier properties and an overall migration value below the permitted limit (10 mg/dm2), indicating that the thus-prepared biocomposite films might potentially be applied to environmentally friendly food packaging.
科研通智能强力驱动
Strongly Powered by AbleSci AI