化学
脱羧
氧化脱羧
键裂
碘
肉桂酸
氧化磷酸化
过氧化物
劈理(地质)
氧化裂解
氧气
药物化学
立体化学
有机化学
催化作用
生物化学
岩土工程
断裂(地质)
工程类
作者
Parbin Rahman,Nilanjana Chakraborty,Bhisma K. Patel,Kamal Krishna Rajbongshi
标识
DOI:10.1021/acs.joc.4c00585
摘要
An iodine-promoted C═C bond cleavage with concomitant decarboxylation and cross-coupling between cinnamic acids and NH-sulfoximines has been developed. This reaction proceeds via selective C═C bond cleavage, followed by decarboxylation and oxidative sulfoximidation. This metal- and base-free protocol involves dioxygen as the source of oxygen, which is facilitated by tert-butyl hydroperoxide (TBHP) as the oxidant affording N-aroylated sulfoximines with good functional group tolerance and good yields.
科研通智能强力驱动
Strongly Powered by AbleSci AI