化学
成核
结晶
纳米技术
纳米尺度
化学物理
药物输送
纳米孔
有机化学
材料科学
作者
Alan Braschinsky,Jonathan W. Steed
标识
DOI:10.1016/j.ccr.2022.214840
摘要
Confinement chemistry is a growing field with many potential applications in the synthetic, catalytic and especially pharmaceutical industries. Confinement of materials can reveal novel properties as compared to their bulk. They can also give insight into the nucleation and crystallization processes at the nanoscale. In this review, we focus on enclosed molecular clusters, from small aggregates to nucleation effects and ultimately crystallization within confining matrices such as metal–organic frameworks (MOFs), discrete cages, nanopores and droplets ranging from 5 Å to 2 mm. This review aims to impact on the discovery of new drug solid forms, drug delivery, crystal engineering, water harvesting, and gas capture among other topics.
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