电解质
石墨
碳酸乙烯酯
材料科学
锂(药物)
电化学
电池(电)
化学工程
电极
锂离子电池
溶剂
无机化学
化学
有机化学
复合材料
功率(物理)
物理化学
内分泌学
工程类
物理
医学
量子力学
作者
Behrooz Mosallanejad,Mehran Javanbakht,Zahra Shariatinia,Mohammad Akrami
出处
期刊:Batteries
[MDPI AG]
日期:2022-10-02
卷期号:8 (10): 152-152
被引量:4
标识
DOI:10.3390/batteries8100152
摘要
In this work, phenyl methanesulfonate (PMS) is evaluated as an additive to enhance the cyclic stability of lithium-ion batteries (LIBs) based on a graphite electrode. According to the theoretical results obtained from density functional theory (DFT) calculations, PMS possesses a lower reduction potential compared to the cyclic carbonate electrolyte solvent. Hence, this compound is foreseen to be reduced before ethylene carbonate (EC) and form a solid electrolyte interphase (SEI) layer on the graphite electrode. The cyclic stability of Li/graphite battery is promoted considerably by adding a low dose of PMS to the electrolyte. The capacity retention of the Li/graphite half-cell is incredibly improved to about 100% after 35 cycles at room temperature. The results acquired from the electrochemical and surface characterization tests corroborate that an electrolyte with PMS is capable of forming a thinner SEI layer compared to the electrolyte devoid of an additive, which can dramatically lessen the interfacial resistance. Moreover, the results show that the graphite sheets are disguised under a myriad of PMS reductive deposits, which can neutralize the catalytic activity of prismatic surfaces.
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