沸石咪唑盐骨架
咪唑酯
吸附
选择性
金属有机骨架
化学
选择性吸附
铯
表面改性
化学工程
亚铁氰化物
环境修复
无机化学
朗缪尔吸附模型
有机化学
污染
催化作用
物理化学
生态学
工程类
生物
电极
作者
Quynh Thi Ngoc Le,Kuk Cho
标识
DOI:10.1016/j.jcis.2020.08.017
摘要
137Cs is one of the most hazardous radionuclides in nuclear waste owing to its toxicity. Developing an adsorbent for Cs+ with a high capacity and selectivity is a challenging task. A metal-organic framework (MOF) is a material with a high surface area that has been widely applied in wastewater treatment. Exploiting the affinity between ferrocyanide (FC) and Cs+, zeolitic imidazolate framework-8 (ZIF-8) was chemically functionalized with FC, ZIF-8-FC to selectively capture Cs+. After functionalization, ZIF-8-FC has a hollow morphology and small FC related crystals, which might result in better migration of Cs+ inside ZIF-8-FC. This synergistic effect was proven by the Qmax of ZIF-8-FC, 422.42 mg g-1, which is 15.9 times higher than that of ZIF-8. Additionally, ZIF-8-FC retained its good adsorption performance within a pH range of 3-11 and an excellent Cs+ selectivity even in artificial seawater conditions. The structure of ZIF-8-FC after adsorption proves its stability. Furthermore, the thermodynamic adsorption implied that higher temperatures are more favorable for Cs+ uptake. This work demonstrates the remarkable adsorption and selectivity of ZIF-8-FC, which make it a promising candidate for remediation of radioactive Cs+.
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