材料科学
钛酸钡
异质结
光致发光
拉曼光谱
色素敏化染料
太阳能电池
光电子学
钙钛矿(结构)
化学工程
光学
物理化学
化学
电解质
物理
工程类
电介质
电极
作者
Tatiane S. Lilge,Ananda Ramires das Neves Stigger,Cristian Dias Fernandes,Luciano Timm Gularte,Cristiane W. Raubach,Sergio Cava,Pedro Lovato Gomes Jardim,Mário E.G. Valério,Mário L. Moreira
标识
DOI:10.1016/j.ceramint.2019.10.227
摘要
In this work, we explored the properties of Barium Titanate (BaTiO3) for application in photoanodes. Unlike other works that used heterojunction, we developed a solar cell by combining Titanium Dioxide (TiO2) and BaTiO3 without sensitization. The increase of Voc in the cell with heterojunction may be explained with TiO2 acted as a blocking layer and as a charge acceptor from BaTiO3, improving the photovoltaic response of the cells, even without dye. For comparison, we developed a Dye-Sensitized Solar Cell (DSSC) by using Barium Titanate (BaTiO3) photoanodes with dye (N-3). The compounds used in the cells has been synthesized with: the microwave-assisted hydrothermal method for BaTiO3 and the Pechini method for TiO2. We use the techniques spin coating for TiO2 layer deposition and doctor blade for BaTiO3 layer. Typical features of a tetragonal structure were revealed by Raman and XAS spectroscopy, suggesting a non-centrosymmetric Ti atom in the TiO₆ octahedron. This result may generate localized states into the band gap. UV–vis absorption and photoluminescence indicate low recombination of the electron-hole pair. That may contribute to the photovoltaic behavior if associated with heterojunctions.
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