化学
苯乙炔
四聚体
分子
桥接(联网)
苯
结晶学
磷化氢
金属
光化学
立体化学
有机化学
计算机网络
计算机科学
酶
催化作用
作者
L. Naldini,Francesco Demartin,Mario Manassero,Mirella Sansoni,Gloria Rassu,Maria Antonietta Zoroddu
标识
DOI:10.1016/0022-328x(85)87051-0
摘要
The [CuPPh3CCPh]4 tetramer, obtained by treatment of [Cu(PPh3)2BH4] with phenylacetylene and KOH (molar ratio 1/1/1) in 1/1 benzene/benzyl alcohol, consists of a tetrahedral skeleton of metal atoms bonded to four terminal phosphine molecules and to four μ-3 -bridging phenylacetylide ligands which behave essentially as 2e donors.
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