Solubilities, Vapor Pressures, Densities, and Viscosities of the (Water + Lithium Bromide + Lithium Iodide + Lithium Chloride) System

化学 溴化锂 锂(药物) 氯化锂 碘化锂 沸点 蒸汽压 碘化物 溴化物 分析化学(期刊) 绝对偏差 热力学 无机化学 物理化学 色谱法 有机化学 电极 统计 数学 电解质 医学 内分泌学 物理 热交换器
作者
Kee‐Kahb Koo,Hyung-Rae Lee,Siyoung Jeong,Young-Sam Oh,Dal-Ryung Park,Youngsoon Baek
出处
期刊:Journal of Chemical & Engineering Data [American Chemical Society]
卷期号:43 (5): 722-725 被引量:9
标识
DOI:10.1021/je980063l
摘要

Measurements of thermophysical properties of the (water + lithium bromide + lithium iodide + lithium chloride) system (LiBr:LiI:LiCl = 4.5:1:2 by mole ratio) were performed as functions of concentration and temperature. Solubilities were measured by a visual polythermal method at temperatures from (248.59 to 350.46) K. Regression equations were obtained with a least-squares method, and the average absolute deviations of the calculated values from the experimental data were 0.10% (solution temperature < 284.59 K) and 0.12% (temperature ≥ 284.59 K), respectively. The vapor pressures were measured by a boiling point method at lithium salts concentrations from (50.0 to 70.0) mass % and temperatures from (318.36 to 455.75) K. The experimental data were correlated with an Antoine-type equation. The average absolute deviation of the calculated values from the experimental data was 1.83%. Densities and viscosities were measured at concentrations from (50.0 to 64.0) mass % and temperatures from (283.15 to 333.15) K. Regression equations for densities and viscosities were obtained with a least-squares method, and the average absolute deviations of the calculated values from the experimental data were 0.08% and 0.87%, respectively.
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