绝对(哲学)
绝对电极电位
电极
参比电极
标准电极电位
电极电位
化学
分析化学(期刊)
电化学
物理化学
色谱法
认识论
哲学
标识
DOI:10.1016/0013-4686(90)85069-y
摘要
A unifying derivation of the various concepts of “absolute” electrode potential is provided starting from a simple electrochemical cell. The approach proves that all kinds of “absolute” potential are implicit in the thermodynamics of the cell and all have the same conceptual validity. Therefore, the relevant question is not which is the true “absolute” electrode potential, but which provides the most convenient reference for a practical impact.
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