Surface Hydrophobic Modification of Biochar by Silane Coupling Agent KH-570

生物炭 热重分析 接触角 表面改性 化学工程 渗滤液 材料科学 化学 环境化学 热解 复合材料 有机化学 工程类
作者
Muxi Zhang,Hongxiang Zhu,Beidou Xi,Yuxin Tian,Xiaojie Sun,Hongxia Zhang,Beibei Wu
出处
期刊:Processes [Multidisciplinary Digital Publishing Institute]
卷期号:10 (2): 301-301 被引量:48
标识
DOI:10.3390/pr10020301
摘要

Biochar-amended soil cover (BSC) in landfills can improve the oxidation of methane. However, adding biochar can cause a larger amount of rainwater to enter the soil cover and landfill because it increases the permeability of the soil cover, which increases leachate production. Improving the hydrophobicity and waterproof ability of BSC is expected to reduce rainwater that goes into landfills. Silane coupling agent KH-570 is used to modify biochar to improve its hydrophobicity and waterproof ability after being added to the soil cover. The waterproofness of hydrophobic biochar-amended soil cover (HBSC) was studied by conducting a precipitation simulation test. Results showed that the optimum hydrophobicity of the surface-modified biochar was obtained when the mass fraction of KH-570 was 7%, the biochar dosage was 7 g, and the modification temperature was 60 °C. In these conditions, the contact angle was 143.99° and the moisture absorption rate was 0.10%. The analysis results of thermogravimetric, X-ray diffractometer and scanning electron microscopy before and after the biochar modification showed that KH-570 formed a hydrophobic organic coating layer on the biochar surface, indicating that the surface hydrophobic modification of biochar was successfully carried out by silane coupling agent. The waterproof ability of HBSC was significantly better than that of BSC in the simulated precipitation test.
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