Catalytic Kinetics Regulation for Enhanced Electrochemical Nitrogen Oxidation by Ru‐Nanoclusters‐Coupled Mn3O4 Catalysts Decorated with Atomically Dispersed Ru Atoms

Electrochemical N2 oxidation reaction (NOR), using water and N2 in the atmosphere, represents a sustainable approach for nitric production to replace the conventional industrial synthesis with high energy consumption and greenhouse gas emission. Meanwhile, owing to chemical inertness of N2 and sluggish kinetics for 10-electron transfer, emerging electrocatalysts remain largely underexplored. Herein, Ru-nanoclusters-coupled Mn3 O4 catalysts decorated with atomically dispersed Ru atoms (Ru-Mn3 O4 ) are designed and explored as an advanced electrocatalyst for ambient N2 oxidation, with an excellent Faraday efficiency (28.87%) and a remarkable NO3- yield (35.34 µg h-1 mg-1cat. ), respectively. Experiments and density functional theory calculations reveal that the outstanding activity is ascribed to the coexistence of Ru clusters and single-atom Ru. The synergistic effect between the Ru clusters and Mn3 O4 can effectively activate the chemically inert N2 , lowering the kinetic barrier for the vital breakage of N≡N. The intensive *OH supply and enhanced conductivity are used to regulate the catalytic kinetics for optimized performance. This work provides brand-new ideas for the rational design of electrocatalysts in complicated electrocatalytic reactions with multiple dynamics-different steps.