阳极
涂层
锌
三嗪
极化(电化学)
材料科学
化学工程
金属
电解质
水溶液
电偶阳极
电流密度
无机化学
电极
化学
纳米技术
高分子化学
阴极保护
冶金
有机化学
物理化学
工程类
物理
量子力学
作者
Gaopeng Li,Xinlu Wang,Shuhui Lv,Jinxian Wang,Xiangting Dong,Dongtao Liu
标识
DOI:10.1016/j.cej.2022.138116
摘要
The development of aqueous zinc-ion batteries is greatly hindered by the intrinsic defects of Zn metal anodes, such as uncontrollable dendrite growth and complicated side reactions. Herein, a covalent triazine framework (CTF), with abundant zinc ion transfer channels and strong chemical stability, is fabricated as a coating layer of zinc anodes to address these problems. The CTF layer not only regulates uniform Zn2+ transport path but also effectively separates zinc anodes from bulk electrolytes, thereby preventing the occurrence of side reactions. Moreover, the triazine ring can serve as zincophilic sites to enhance Zn deposition kinetics. Thus, the CTF-protected Zn anode enables a Zn//Zn symmetric cell to achieve a long cycle lifespan of over 7000 h, about 40 times larger than that of bare Zn anodes. This symmetric cell also has a low and stable voltage polarization of 36 mV even after 3000 h. Meanwhile, the full cell coupled with calcium-doped V2O5 exhibits capacity retention of 66.7 % after 300 cycles at a current density of 1 A g−1, while the cell with bare Zn anode could only retain 24.3 % of capacity under the same condition. This work provides a promising method to address the anode problems in metal-ion batteries.
科研通智能强力驱动
Strongly Powered by AbleSci AI