纳米传感器
材料科学
光致发光
电化学
X射线光电子能谱
检出限
纳米颗粒
共价键
透射电子显微镜
带隙
纳米技术
分析化学(期刊)
光化学
化学工程
化学
物理化学
电极
光电子学
有机化学
工程类
色谱法
作者
Hamidreza Behboudi,Mehrab Pourmadadi,Meisam Omidi,Moones Rahmandoust,Seyed Omid Ranaei Siadat,Javad Shabani Shayeh
标识
DOI:10.1016/j.surfin.2021.101710
摘要
Thiols play critical roles in biological processes. Here, a facile hydrothermal synthesis approach was used for fabrication of flourescent Cu-carbon dots (Cu-CDs), to be employed as accurate thiol Nanosensors. The obtained Cu-CDs were characterized using transmission electron microscopy, UV–visible, photoluminescence and X-ray photoelectron spectroscopy scannings. The highest-occupied- and lowest-unoccupied- molecular-orbitals and the pertaining energy band gap were achieved using analytical chemistry density functional theory. Electrochemical performance of Cu-CDs showed the capability of the fabricred nanoparticles for accurate, sensitive, and selective nanosensing of thiols, as both electrochemical and optical detection tools. The electrochemical peak of Cu-CDs were selectively, rationally and intensively suppressed by thiols, due to the strong electrostatic interaction and covalent bonding between the NH2 functional groups of the Cu-CDs and -SH groups of thiols. On the other hand, the blue photoluminescence emission of Cu-CDs rationally increased, due to detachment of Cu ions from the edges of Cu-CDs in the existance of thiols. According to the above description, the limit of detections (LODs) of 1 nM was achieved, introducing such-prepared Cu-CDs nanosensors, as simple, fast, low-cost, sensitive and selective tools for thiol detection.
科研通智能强力驱动
Strongly Powered by AbleSci AI